Reflexive: f(x)≤f(x) for every x, so f≼f.
Antisymmetric: if f≼g and g≼f, then for every x we have f(x)≤g(x) and g(x)≤f(x), so f(x)=g(x) for all x, i.e. f=g.
Transitive: if f≼g and g≼h, then for every x we have f(x)≤g(x)≤h(x), so f≼h.
All three properties hold, so ≼ is a partial order.
It is not total. Take f(x)=x and g(x)=−x. At x=1: f(1)=1>−1=g(1), so f≼g. At x=−1: f(−1)=−1<1=g(−1), so g≼f. The two functions are incomparable. ■